アゾジカルボンアミドと酸化剤の反応(物質生命化学科)

Abstract

Although the thermal decomposition mechanism of azodicarbonamide is not clarified, it is known that evolved of carbon monoxide and ammonia gas from thermal decomposition. By this research, thermal analysis was conducted for elucidation of thermal decomposition mechanism of azodicarbonamide, and reaction mechanism was examined. Moreover, in order to also consider evolving gas component improvement, thermal decomposition mechanism of oxidizer mixture was considered and the following results were obtained. 1) In thermal decomposition of azodicarbonamide simple substance, it was identified under the radical influence which carries out middle generation that a reaction changes with decomposition temperature, and also the near reaction mechanism was presumed. 2) When metal oxide was mixed, the effect which is generated in a reaction and which controls generating of carbon monoxide by the reaction of metal oxide and radical was identified. 3) Also in the oxidizer as which an effect was not regarded by the 2 component mixture, when raising the activity in a low temperature region by adding the catalyst, an effect was identified.