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Please use this identifier to cite or link to this item: http://hdl.handle.net/11178/4626

Title: 水とアルコール混合溶液の^1H-NMRスペクトル測定(物質生命化学科)
Other Titles: ^1H-NMR spectrum measurement of water and alcohol mixed solution(DEPARTMENT OF APPLIED CHEMISTRY AND BIOCHEMISTRY)
Authors: 松浦, 正樹
東, 直人
楢山, 芳彰
神尾, 克彦
米光, 直志
Matsuura, Masaki
HIGASHI, Naoto
NARAYAMA, Yoshiaki
KAMIO, Katsuhiko
YONEMITSU, Tadashi
マツウラ, マサキ
ヒガシ, ナオト
ナラヤマ, ヨシアキ
カミオ, カツヒコ
ヨネミツ, タダシ
九州産業大学工学部工業化学科 / 九州産業大学工学部工業化学科 / 九州産業大学工学部工業化学科 / 九州産業大学工学部物質生命化学科 / 九州産業大学工学部物質生命化学科
Keywords: NMR
Chemical shift
Hydrogen bond
Methanol
Ethanol
Propanol
IsoPropanol
t-Butanol
Ethylene Glycol
Glycerin
Issue Date: Dec-2006
Publisher: 九州産業大学工学部
Abstract: ^1H NMR spectrum measurement was carried out on the mixed solution of water and alcohols. The effect of the hydrophobicity of the alcohol molecule for the hydrogen bond structure which water molecule had formed was examined. It was the order of the t-butanol>isopropanol>propanol>ethanol>methanol that the alcohol was low-densified and that it weakens the hydrogen bond between water molecule. The result of reversely intensifying the hydrogen bond was obtained ehylene glycol and glycerin. This seemed to form the hydrogen bond with the water, since it mainly has hydroxyl group.
URI: http://hdl.handle.net/11178/4626
Appears in Collections:第43号

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